A - - - - UNOIACIO# l'IIONICCIOII Gerencia de Transporte y ...amtwatersolutions.com/cedula...

SUBDIRECCIÓN DE GESTIÓN DE PROYECTOS TÉCNICOS/ GERENCIA DE GESTIÓN DE PROYECTOS TECNOLÓGICOS

CÉDULA DE EVA LUACIÓN "FLOCULACIÓN IÓNICA PARA TRATAMIENTO DE AGUA CONGÉNITA"

A PEMEX . . . . . . Página 1 ,Ei,) Num. Dictamen SGRT GGPT PT 26 2013 Tipo de Dictamen: ANALISIS DE PRUEBA Evaluac1on: APROBADA

d UNOIACIO# r l'IIONICCIOII

- - - -e 9

JULIO/ 2013

Componente INSTALACIONES Área/Unidad Administrativa: Gerencia de Transporte y Distribución de Hidrocarburos (GTDH)

APLICACIÓN DE LA TECNOLOGÍA OBSERVACIONES FECHA COMPROMISO

SITUACION ACTUAL SITUACION POSTERIOR CONCLUSIONES RECOMENDACIONES I PREVIO A MASIFICAR

1. Criterio de Evaluación "Parámetros establecidos en las Normas Mexicanas oara vertimiento de aoua"

. ./ resultados-cocrespondientes al

Derived from the problem of the forecast of increased production of congenital water present in the crude produced in the maritime and terrestrial fields of Pemex exploration and production (PEP), the test "Ionic flocculation for congenital water treatment" was carried out. the facilities of the maritime terminal Dos Bocas.In order to determine the functionality of the congenital water treatment plant of the company FI ESCORPION, the evaluation was carried out through the following actions: The physicochemical analysis and salt content of the water streams at the outlet of the water treatment plant installed in the TMDB (marine diffuser and TV-5007) were analyzed to determine the present value of contaminants and compare them with the parameters that they mark the official Mexican norms; NOM-001-SEMARNAT-1996, fishing exploitation section, navigation and other uses (A); NOM-143-SEMARNAT-2003, section 5.1.5.

TEST A

NOM-1'43-SEMARNAT-2003

The results shown in Table 3 correspond to the laboratory analysis for each parameter of the samples taken at the exit of the congenital water treatment plant of the company FI ESCORPION (Test A) referring to the Mexican standard NOM-143-SEMARNAT- 2003

Supervisor del Área Técnica Responsable de la GTDH -RMSO

lng. Eduardo Elías Rayón

E.O. Gerenc�p�rte y Distribución de

,ij./arburos, RMSO

JUM

\ �,

�

Supervisor de la GTDH-RMSO

Aceite, Sector Dos Bocas

CONCLUSIONSAnalyzing the results that AU provided to the GGPT of the tests I carried out in the TMDB facilities, in the marine diffuser (test A) and TV 5007 (Test B), backed with the 2071 and 2072 jobs signed by Mr. Alejandro Peña Calderón; it concludes:

According to the results issued by the Laboratory of the Microanalysis Group S.A. of C.V. of the test A carried out from February 14 to 23, 2012 by the OT FI SCORPION in the marine diffuser of the facilities of the TMDB and backed up with the official letter 2071 it is verified that the levels

The OT must demonstrate convincingly and prior to the process of massification the compliance scenarios with the limit established in the parameter of total dissolved solids (SDT), according to NOM-143-SEMARNAT-2003.

The UA in the future must adhere to perform technological recognition processes within the regulatory framework authorized by the DG of PEP in March 2010.

The Au, in case of acquiring this technology, must continuously monitor the quality of the results, mainly from the first 30 days.

In Pemex Exploration and Production (PEP) strategies have been established to identify the best technological opportunities and overcome the different challenges imposed by the current exploitation of the deposits. where hydrocarbons are produced with a high percentage of water.

The Dos Bocas Maritime Terminal (TMDB) receives crude from offshore and terrestrial complexes for its conditioning. storage, distribution and transport for export or national consumption. Due to the maturation of current fields, congenital water production has increased substantially in recent years becoming one of the most important challenges for PEP.

The official Mexican norms related to the management and disposal of wastewater and congenital water (NOM-001-SEMARNAT-1996 and NOM-143-SEMARNAT-2003) establish the maximum permissible limits of contaminants to be discharged to the receiving body and / or injection to bodies \ of capture. The TMDB has an effluent treatment plant. the treated water is available actuallYleQ! .e <!! injectors wells and / or to the sea through a marine diffuser.

In order to meet the needs of PEP, the test called "Lonic Flocculation for Congenital Water Treatment" was carried out in the facilities of the TMDB. This test was carried out in two points defined by TMDB personnel. the marine diffuser (Test A), and the TV 5007 (Test B).


CÉDULA DE EVALUACIÓN "FLOCULACIÓN IÓNICA PARA TRATAMIENTO DE AGUA CONGÉNITA"

A PEMEX . . 6 . d . • 1 . • O Página 2

JE!'i, Num. Dictamen SGRT_GGPT_PT_2 _2013 Tipo e Dictamen: ANALISIS DE PRUEBA Eva uacIon: APR BADA d g anouao• r NOO«CJOII e

Componente INSTALACIONES Área/Unidad Administrativa: Gerencia de Transporte y Distribución de Hidrocarburos (GTDH) J��I�/

· · FECHA APLICACION DE LA TECNOLOGIA OBSERVACIONES COMPROMISO SITUACION POSTERIOR CONCLUSIONES RECOMENDACIONES PREVIO A MASIFICAR

RESULTADOS DE ANÁLISIS DE PARAMETROS

PARAMETI!OS NORMA PROMEDIO '-'

DIFERENCIA

SITUACION ACTUAL ESULTADOS DE ANÁUSIS DE PARAMETROS

mg/ e PM SALIDA•

NORMA PROMEDIO PARAMETI!OS

PM ENTRADA· Hidrocarburos Totales 40 NO· 40.00 Temperatura <·cJ 40 29.25• 1-------------_._----+-----1

. . . Aceites y grasas (mg/I) 15 10.ss• Sóhdos Disueltos Totales 32000 73n6.s:,_ 41776.S HTP'S (mg/II 40 30.68' . . . . . .

. f Información vahdada en el oficio 2071 em,t,do por "'.-Gerencia de Materia lotante AU AU' . . . . - ,� Transporte y Distnbuc,ón de H1drocarburos-MSO, el 05 de-ma de _ Sólidos Sedimentables (mg/I) 1 8.75' 2012_ Solidos Suspendidos Totales (mg/I) 150 628.50' . ..._ . . . PM - Promedio Mensual NO- No ddectado � Solidos Totales Disueltos (mg/I) 32000 91110.25' �------------,--------,----'......_ pH 5 -10 1.16' \ � � 080 (mg/lJ 150 370_58• Tabla 3. Resultado_s

..,déañalisis-de laboratorio aJa salida de la planta,

. NOM-1-4:tsEMARNAT-2003,Prueba A. Nitrogeno Total (mg/I) N.A. 63.35' '\ Fósforo Total (mg/1) N.A o.53• • orato

Resultados emitidos por el Labrio del Grupo Microanélisis, S.A. de Arsénico (mg/I) 0.1 0.0188' cadmio (mg/l) 0_1 0_00078• Cianuro (mg/I) 1 O.NO' Cobre (m 1) 4 o.1r

•

�

Cromo (mg/l) o.s B.o7 < Mercurio (mg/I) o.01 o.0001s•

N. 1 < g/lJ 2 NO' �

,que m .-.. Plomo (mg/ll 0_2 0_02375• . , Zinc (mg/II 10 o.l.37-s• ..._ \ Coliformes Fecales (NMP/100 ✓ 1000 58 34•,

\ \ NOM�1-SEMARNAT-1996

Huevos de Helminto (Huevos/1),,- . E- Entrada S-Salida AU-Ausente \ -

Tabla 1. Resultados.de los,análisis de laboratorio a la entrada de la / ,"Planta, Prueba A. �

'Resultados emitidos por el Laboratorio del Grupo Microanálisis. S.A. de C. v. �

Responsable Oirecto_del

Supervisor del Área Técnica Responsable de la GTDH -RMSO r de la GTDH-RMSO

M.1. Jes "---:::;�:::�

◄;r;l�-:/J;.b�"'[;�(H;¡,t,��Ji<:C:�[V lng. Eduardo Elías Rayón

GGM JUM

eite, Sector Dos Bocas

The content of total hydrocarbons at the exit of the congenital water treatment plant of the FI ESCORPION company was not detected, as a result it complies with the regulations and in the case of the content of Total Dissolved Solids is above the permissible limit established in the standard (32,000 mg / l).

Table 4 shows the results corresponding to the laboratory analysis for each parameter of the samples taken at the exit of the congenital water treatment plant of the company FI ESCORPION (test A) referring to the Mexican standard NOM-001- SEMARNAT-1996, it can be observed that all the parameters evaluated are within the norm.

of contaminants are within the maximum permissible limits established by the official Mexican standard NOM-001-SEMARNAT-1996. In relation to the NOM-143-SEMARNAT-2003 does not comply with the content parameter of total dissolved solids.According to the results issued by the Lab Core Lab Operations S.A. of C.V. of the test B carried out from June 11 to 23, 2012 on TV 5007 of the TMDB facilities by the OT FI SCORPION and backed up with the 2072 official verification that the levels of contaminants

The UA, responsible for wastewater discharges, must process before the corresponding government agencies the approval of its environmental impact statement and the request to obtain the concession title for the discharge of water to the sea.The UA should consult the treatment prices per barrel of water treated in accordance with those reported in the business case studies prepared by the GGPT.The TO must provide the calculation memory of the plant efficiency factors related to their percentages of removal of contaminants.

analysis for each parameter of the samples taken at the entrance of the congenital water treatment plant of the Cía. FI SCORPION for Test A (marine diffuser).



A PEMEX Página 3

_E.J Núm. Dictamen SGRT_GGPT_PT_26_2013 Tipo de Dictamen: ANÁLISIS DE PRUEBA Evaluación: APROBADA EJNOCAC/OII r NOHCC/OII l--------+-----------+------------------------'---------'----------t--d_e_9

-:--""i

JULIO/ 2013 Componente INSTALACIONES Área/Unidad Administrativa: Gerencia de Transporte y Distribución de Hidrocarburos (GTDH)

APLICACIÓN DE LA TECNOLOGÍA OBSERVACIONES FECHA

COMPROMISO

SITUACION ACTUAL

Table 2 shows the results corresponding to the analysis for each parameter of the samples taken at the entrance of the congenital water treatment plant of Cia. FI ESCORPIÓN for Test B (TV 5007).

RESULTADOS DE ANÁLISIS DE PARAMETROS

NORMA PROMEDIO PARAMETROS

PM ENTRA.DA••

Temperatura ("C) 40 31_45••

Aceites y grasas (mg/1) 15 56.45 ..

HTP'S (mg/1) 40 349.82 ..

Materia flotante AU AU .. Sólidos Sedimenta bles (mg/1) 0.1 .. Sólidos Suspendidos Totales 150 195.36 .. (mg/1)

Sólidos Totales Disueltos (mg/1) 32000 96210.73 .. pH 5-10 8.29 ..

DBO(mg/1) 150 227.37 .. Nitrógeno Total (mg/1) N.A. 94.05••

Fósforo Total (mg/1) N.A NO º ' Arsénico (mg/1) 0.1 NO••

Cadmio (mg/1) 0.1 0.00085° 0

Cianuro (mg/1) 0.0664 .. Cobre (mg/11 4 0.211·· Cromo (mg/1) 0.5 0.9734"

Mercurio (mg/1) 0:01 0.00161º

Níquel (mg/1) � 0.373 ..

Plomo (mg/1) 0.2 0.0067** Zinc (mg/1) 10 0.2164•*

Coliformes Fecales (NMP /100) 1000 224.90ºº

Huevos de Helminto (Huevos/l) S Huevos/1 1.00•· E- Entrada S-Salida AU-Ausente

M.I. Jes ·

SITUACION POSTERIOR CONCLUSIONES RECOMENDACIONES

RESULTADOS DE ANÁLISIS DE PARAMETROS NORMA PROMEDIO

PARAMETROS SAUDA* PM

Temperatura (ºC) 40 28.20' Aceites y grasas (mg/1) 15 <12'

HTP'S (mg/1) 40 NDº

Materia flotante AU AU' Sólidos Sedimenta bles (mg/1) Sólidos Suspendidos Totales

(mg/1) pH

DIFERENCIA

11.8 ,3

40

DBO(mg/1) "-'"-'-----+----+-----+-----'k

Fósforo Total ( 0.0965

0.1 NO" 0.1

NO* 1

4 0.018' 3.982

0.5 0.0133' 0.487 0.01 0.0001· 0.0099

2 ND' 2

0.2 0.007' 0.193

10 0.023º 9.977

1000 24.11 • 975.89

5 <l.00' 4 Información validada en el oficio 2071 emitido por la Gerencia de

Transporte y Distribución de Hidrocarburos•MSO, el 05 de marzo de 2012.

- Entrada S-Salida AU-Ausente NO- No Detectado PM- Promedio Mensual

Tabla 4. Resultados de análisis de laboratorio a la salida de la planta. NOM-001-SEMARNAT-1996. Prueba A.

•Resultados emitidos por el laboratorio del Grupo Microanálisis, S.A. de C. V.

PREVIO A MASIFICAR

Responsable de la GTDH ·RMSO Supervisor de la GTOH-RMSO

JUM

are within the maximum permissible limits established by the official Mexican standard NOM-001-SEMARNAT-1996. In relation to the NOM-143-SEMARNAT-2003 does not comply with the content parameter of total dissolved solids.

For the above, it is declared APPROVAL having achieved acceptable levels of efficiency.The cost reported by the OT for sale is $ 4.64 usd / b per barrel and on rent $ 6.0 usd / b of treated water.



.Á PEMEX , - , Página 4

EiiJ Num. Dictamen SGRT_GGPT_PT_26_2013 Tipo de Dictamen: ANAUSIS DE PRUEBA Evaluacion: APROBADA d g UNOIACIOII r rtOOIICCIOI e

JULIO/ 2013


APLICACIÓN DE LA TECNOLOGÍA OBSERVACIONES FECHA COMPROMISO

SITUACIÓN ACTUAL planta, Prueba B.

.. Resultados emitidos por Core Lab Operations S.A. de C. V.

SITUACIÓN POSTERIOR CONCLUSIONES

TEST B NOM-143-SEMARNAT-2003 The results shown in table 5 correspond to the laboratory analysis for each parameter of the samples taken at the exit of the congenital water treatment plant of the company FI ESCORPION (Test B) referred to the Mexican standard NOM-143-SEMARNAT-2003.

DIFERENCIA

39.715

Sólidos Disueltos Totales 32000 85830.55° 53830.55

Información validada en\.... el oficio 2071 emitido por la Gerencia de Transporte y Distribución de Hidrocarburos-MSO, el 26 de junio de 2012,

PM - Promedio Mensual

Tabla✓5. Resultados de análisis-de laboratorio a la salida de la planta, � NOM-143-SEMARNAT-2003, Prueba B .

.. Resultados emitidos por Core Lab Operations S.A. de C. V.



RECOMENDACIONES I PREVIO A MASIFICAR


Transpo�drocarburos Aceite, Sector Dos Bocas

JUM



A PEMEX . . . d . -1 .• Páginas

J!!i,} Num. Dictamen SGRT_GGPT_PT_26_2013 Tipo e Dictamen: ANALISIS DE PRUEBA Eva uac1on: APROBADA d UNOIIAOO# r noDUCCJOI e 9

JULIO/ 2013



COMPROMISO SITUACION ACTUAL SITUACION POSTERIOR CONCLUSIONES I RECOMENDACIONES PREVIO A MASIFICAR

The content of total hydrocarbons at the exit of the congenital water treatment plant of the company FI ESCORPION was 0.785 mg / l as a result it complies with the regulations and in the case of the content of Total Dissolved Solids is above the permissible limit established in the standard (32,000 mg / l).

NOM-001-SEMARNAT-1996




Table 6 shows the results that correspond to the

laboratory analysis for each parameter of the

samples taken at the exit of the congenital water treatment plant of the company FI ESCORPION (Test B) referred to the Mexican standard NOM-001- SEMARNAT-1196, it can be observed that all the

parameters evaluated are within the norm.

SUBDIRECCIÓN DE GESTIÓN DE PROVECTOS TÉCNICOS/ GERENCIA DE GESTIÓN DE PROVECTOS TECNOLÓGICOS


..é PEMEX Núm. Dictamen SGRT_GGPT_PT_26_2013 Tipo de Dictamen: ANÁLISIS DE PRUEBA Evaluación: APROBADA Pád

gina 7 UNOUCJOII r NOO«C/OII e 9

JULIO/ 2013



COMPROMISO SITUACION ACTUAL

M.I. Jesús

GGM

SITUACION POSTERIOR CONCLUSIONES I RECOMENDACIONES PREVIO A MASIFICAR

Cost comparisonlInfluent: Congenital waterTotal volume to be treated: 1500,000 bpd.Effluent: Water that complies with standards NOM-001-SEMARNAT-1996 and NOM-143-SEMARNAT-2003.Electric power consumption: 1.32 kW per barrel treated per day.Dimensions: 3,600 m2 x 3m high.Approximate weight: 3,800 tonsRequired area: 12,000 m2Delivery time: 52 weeks

Guarantee

Upon conclusion of the contracts for the design of the plant, its manufacture, installation and commissioning, the OT will deliver the corresponding bonds.The quality of processed water will be certified through

laboratory analysis results recognized by E.M.A.FI ESCORPION GRUPO CORPORATIVO S.A. of C.V.

guarantees the plant for a period of twelve months counted from the date it is put into operation.In case you have to change the process material of the

plant. Once the guarantee term has expired, the OT will replace the spare parts for 10 years.

Supervisor del ÁreaTécníca Responsable de la GTDH -RMSO


E.O. Gerencia /r�rte � Distribución de �ros,RMSO

Sue_ervísor de la GTDH-RMSO

JUM



A PEMEX , . , ., Páginas .ll!ii,J Num. Dictamen SGRT_GGPT_PT_26_2013 Tipo de Dictamen: ANALISIS DE PRUEBA Evaluac1on: APROBADA

d g EVIOUOO# r l'IIOHCOOII e

JULIO/ 2013

Componente INSTALACIONES Área/Unidad Administrativa: Gerencia de Transporte y Distribución de Hidrocarburos (GTDH}


COMPROMISO SITUACIÓN ACTUAL

M,I, Jes,

SITUACION POSTERIOR CONCLUSIONES I RECOMENDACIONES PREVIO A MASIFICAR

Plant Sale Costs:366,547,494.00 USD (Three hundred sixty-six million five hundred forty-seven thousand four hundred and ninety-four 00/100 U.S. Cy. Dlls.)

labia 7. Costos venta de la planta.

V ,._,.....

Operación

IV Mantenimiento

Administración

Financiamiento

2.62

0.70

0.18

2.50

Tabla 8. Costos renta de la planta.

Costo Total = 6 dólares.


lng, Eduardo Elías Rayón

e y Distribución de ,ros, RMSO


JUM

Table 7 expresses the cost broken down per barrel for the sale scenario of the plant

Income of the plant.

Table 8 shows the cost broken down by barrel for the plant's income.



.. PEMEX Núm. Dictamen SGRT_GGPT_PT_26_2013 Tipo de Dictamen: ANÁLISIS DE PRUEBA Evaluación: APROBADAPá

dgin

9a g

a,iouao• r NOO«CJOII e JULIO/ 2013


SITUACIÓN ACTUAL

APLICACIÓN DE LA TECNOLOGÍA OBSERVACIONES

SITUACIÓN POSTERIOR CONCLUSIONES I RECOMENDACIONES

o

'" ...

- 1.0 o 'o 1.0

s) o.o

u

Cost per ton of inert neutral sludge in its handling and final disposal with laboratory analysis for 10 years is 120.00 USD.

The cost to deliver the sludge for PEMEX disposal is $ 40.00 USD.

In the event that PEMEX has a contract with a company to dispose of the sludge, these will not generate any expense with the company FI ESCORPION Grupo Corporativo S.A. of C.V.

COMPARATIVE OF SALES COSTPT FI Escorpión en la TMDB

• ■ •

10 2S SO 100 t.SO 300 600 900

Volumen de agua a tratar (mbpd)

�Venta

-.Renta



FECHA COMPROMISO

PREVIO A MASIFICAR

A - - - - UNOIACIO# l'IIONICCIOII Gerencia de Transporte y ...amtwatersolutions.com/cedula...

Documents

Transcript of A - - - - UNOIACIO# l'IIONICCIOII Gerencia de Transporte y ...amtwatersolutions.com/cedula...